Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Macroporous Monolith with Polymer Gel Matrix as Continuous-flow Catalytic Reactor
Hikaru MatsumotoHirokazu SetoTakanori AkiyoshiMakoto ShibuyaYu HoshinoYoshiko Miura
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2017 Volume 46 Issue 8 Pages 1065-1067

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Abstract

A macroporous monolith comprising a polymer gel matrix was developed for application in continuous-flow catalytic reactions. Nanosized Pd(0) particles were loaded in a poly(N-isopropylacrylamide)-gel-based monolith by Pd(II) adsorption and subsequent reduction. The permeability of the Pd(0)-loaded monolith was compared with a commercial membrane filter with a pore size of several micrometers. The Pd(0)-loaded monolith exhibited excellent productivity in a continuous-flow Suzuki coupling reaction. Moreover, the Pd(0)-loaded monolith showed sustained performance over a 7-day period without Pd leaching.

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© 2017 The Chemical Society of Japan
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