Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Nickel(0)-catalyzed Coupling Reactions of Carbonyls and Alkenes with Reducing Reagents Giving Six- and Seven-membered Benzocycloalkanols
Yukari HayashiYoichi HoshimotoRavindra KumarMasato OhashiSensuke Ogoshi
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2017 Volume 46 Issue 8 Pages 1096-1098

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Abstract

Nickel(0)-catalyzed coupling reactions of 1,6- and 1,7-enals with triethylsilane have been utilized to synthesize six- and seven-membered silyl-protected benzocycloalkanols. When triethylborane was employed as the reducing reagent, tetralol derivatives were obtained. Results of deuterium-labeling experiments suggest the formation of oxanickelacycles as a key reaction intermediate.

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© 2017 The Chemical Society of Japan
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