Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Palladium-catalyzed Asymmetric Allylic C–H Oxidation for the Formal Synthesis of Gonytolide C
Peng LiuPu-Sheng Wang
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2017 Volume 46 Issue 8 Pages 1190-1192

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Abstract

For the synthesis of Gonytolide C, an enantioselective intramolecular allylic C–H oxidation was applied to afford the chiral chroman framework in good yield and enantioselectivity, and the key step to obtain the lactone moiety was a cascade dihydroxylation/intramolecular lactonization/elimination. This synthesis provides not only a novel synthetic approach to gonytolide C and its epimer, but also a valuable foundation for the asymmetric synthesis of gonytolides A–B.

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© 2017 The Chemical Society of Japan
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