Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Copper-containing DNA–Silica Mineral Complexes for the Asymmetric Diels–Alder Reaction
Sohei SakashitaSoyoung ParkHiroshi Sugiyama
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2017 Volume 46 Issue 8 Pages 1165-1168

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Abstract

In this study, we have generated DNA–silica minerals containing a Cu(ligand) complex and evaluated their utility in asymmetric synthesis. Cu(dmbpy)/DNA–silica mineral could be applied successfully to the Diels–Alder reaction and reused readily for 10 cycles without loss of enantioselectivity.

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© 2017 The Chemical Society of Japan
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