Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
An Alternating Glycopolymer Composed of Carbohydrate-carrying Maleimide and OH-functionalized Vinyl Ether— A New Synthetic Strategy for Glycosaminoglycan Mimics —
Tomomi OtsuboTomonari TanakaJin MotoyanagiMasahiko Minoda
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2019 Volume 48 Issue 5 Pages 465-467

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Abstract

An alternating glycopolymer was synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization of a maltose-carrying maleimide and diethylene glycol mono vinyl ether as the monomers. The maleimide derivative was newly synthesized by click chemistry using maltosyl azide and N-propargyl maleimide. This facile methodology for sequence-control of glycopolymers gives the shortest way to the synthesis of the first alternating glycopolymers as mimics of natural glycosaminoglycans.

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© 2019 The Chemical Society of Japan
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