Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Regiospecificity of Alternating Copolymerization of Cyclic Conjugated Dienes and Oxygen
Eriko SatoShuji TaketaniChisato OmoriHideo HoribeAkikazu Matsumoto
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2019 Volume 48 Issue 5 Pages 445-448

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Abstract

Alternating radical copolymerization of cyclic conjugated diene monomers, i.e., cyclopentadiene and furan, with oxygen were carried out to generate degradable polyperoxides. The cyclopentadiene and furan based-polyperoxides consisted of different regiospecific structures. The regiospecificity of the alternating copolymerization was rationalized by the bond dissociation energies of the carbon-to-oxygen bond of the peroxy radicals based on density functional theory calculations. The thermal degradation behavior of the resulting cyclic conjugated diene-based polyperoxides was also investigated.

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© 2019 The Chemical Society of Japan
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