Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Rhodium(III)-catalyzed β-Arylation and -Alkenylation of α-Trifluoromethylacrylic Acid
Risa YoshimotoYoshinosuke UsukiTetsuya Satoh
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2019 Volume 48 Issue 5 Pages 461-464

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Abstract

The β-arylation and -alkenylation of trifluoromethylacrylic acid with arylboronic acids and alkenes proceed smoothly under rhodium(III) catalysis. The procedures provide useful synthetic routes from readily available building brocks to β-aryl-α-trifluoromethylpropanoic acid and 5,5,5-trifluoro-1,3-butadiene derivatives. Some of the obtained butadienes exhibit strong fluorescence in the solid state.

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© 2019 The Chemical Society of Japan
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