Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Microwave-assisted Tertiary Carbon Radical Reaction for Construction of Quaternary Carbon Center
Ryota SatoRyuji OkamotoTakumi IshizukaAtsushi NakayamaSangita KaranjitKosuke Namba
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2019 Volume 48 Issue 5 Pages 414-417

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Abstract

Microwave-assisted tertiary carbon radical reaction was developed. The reaction of tertiary xanthates with electron deficient alkenes was prompted by microwave irradiation, and various coupling products possessing quaternary carbon centers were obtained in good yields. The reaction was conducted under simple and common radical condition except for microwave irradiation, and the reaction completed within 5 min.

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© 2019 The Chemical Society of Japan
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