Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Regulation of Ni-LAB Crystal Morphology by Organic/Inorganic Deprotonation Agent
Linjuan ChengJianhua YangHammad SaulatJinming LuYan Zhang
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2019 Volume 48 Issue 5 Pages 449-452

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Abstract

Metal-organic framework Ni2(L-asp)2(bipy) (Ni-LAB) crystals with different morphology were prepared by directly mixing metal solution with organic linker solution with assistance of deprotonation agent (DA) and crystallizing at 150 °C for 24 hours. Both metal source and DA played key roles in the formation of crystalline Ni-LAB. Ni-LAB crystals with different morphology were obtained by using various organic/inorganic DA. Single component vapor adsorption experiments indicated that the as-synthesized Ni-LAB crystal S3 exhibits preferential adsorption of methanol (CH3OH) over methyl tert-butyl ether (MTBE).

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© 2019 The Chemical Society of Japan
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