Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Nonplanar and Dynamic Structures of 1,8-Anthrylene–Ethenylene Cyclic Dimers
Masataka InoueTetsuo IwanagaShinji Toyota
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JOURNAL RESTRICTED ACCESS Advance online publication

Article ID: 130765

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Abstract

The title cyclic compounds, synthesized by cross coupling reactions, have nonplanar frameworks as revealed by X-ray analysis and DFT calculations. The barrier to exchange between the nonplanar structures of the mesity derivative was determined to be 34 kJ mol–1 by dynamic NMR method.

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© 2013 The Chemical Society of Japan
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