Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Syntheses of Aldol Products and Cyanohydrins from Carboxylic Acids Using Hydrosilanes, Organosilicon Reagents, and Indium Triiodide Catalyst
Yoshihiro InamotoYoshihiro NishimotoMakoto YasudaAkio Baba
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JOURNALS RESTRICTED ACCESS Advance online publication

Article ID: 130790

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Abstract

Carboxylic acids were applied to an indium triiodide-catalyzed reductive aldol reaction and a reductive cyanation in order to produce aldol adducts and cyanohydrins, respectively, in which the separate addition of two kinds of hydrosilanes was crucial in a combination with either ketene silyl acetals or silyl cyanides.

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© 2013 The Chemical Society of Japan
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