Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Preparation of Nanoribbons of Blue Potassium Molybdenum Bronze
Takamasa NishidaKazuo EdaKazuyuki TakahashiTakahiro SakuraiHitoshi OhtaM. Stanley Whittingham
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JOURNALS RESTRICTED ACCESS Advance online publication

Article ID: 130792

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Abstract

We have successfully prepared nanoribbons of blue potassium molybdenum bronze (K0.3MoO3) from hydrogen molybdenum bronze (H0.3MoO3) by using crystallite splitting induced by solid-phase transformation and subsequent selective growth under hydrothermal conditions. The obtained nanoribbons were single crystals with a size of ca. 100 m×100 nm×10 nm, well-elongated to the crystal b axis that corresponds to the conduction direction as a quasi-one-dimensional metal. A simple deaeration procedure necessary for preparing a single-phase of blue potassium bronze is also given.

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© 2013 The Chemical Society of Japan
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