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Chemistry Letters
Article ID: 160158

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http://doi.org/10.1246/cl.160158

  • Abstracts

A Pd-catalyzed branch-selective decarboxylative allylation of ketone-derived monosubstituted allylic enol carbonates is reported. The use of an ammonium–phosphine hybrid ligand bearing a non-coordinating anion is crucial for obtaining a branched isomer with high regioselectivity.

Copyright © 2016 The Chemical Society of Japan

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