Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Palladium-Catalyzed Branch-Selective Decarboxylative Allylation Using Ion-Paired Ligands
Yoshiyuki HaraYuya KusanoKohsuke OhmatsuTakashi Ooi
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JOURNALS RESTRICTED ACCESS Advance online publication

Article ID: 160158

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Abstract

A Pd-catalyzed branch-selective decarboxylative allylation of ketone-derived monosubstituted allylic enol carbonates is reported. The use of an ammonium–phosphine hybrid ligand bearing a non-coordinating anion is crucial for obtaining a branched isomer with high regioselectivity.

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© 2016 The Chemical Society of Japan

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