Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
TRANSVERSE CONDUCTION AND METAL-INSULATOR TRANSITION IN β-(BEDT-TTF)2PF6
Hayao KobayashiTakehiko MoriReizo KatoAkiko KobayashiYukiyoshi SasakiGunzi SaitoHiroo Inokuchi
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1983 Volume 12 Issue 4 Pages 581-584

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Abstract

In the crystal of β-(BEDT-TTF)2PF6, BEDT-TTF (bis(ethylenedithiolo)tetrathiafulvalene) molecules are arranged side-by-side. The anisotropy of the electrical resistivity shows that β-(BEDT-TTF)2PF6 is the first organic conductor where the conductivity is the largest along the direction parallel to the molecular plane. The metal-insulator transition is observed at 297 K. The thermoelectric power corresponds to that due to the hole conduction in highly correlated system.

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