Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
CRYSTAL STRUCTURE AND ELECTRICAL CONDUCTIVITY OF (Et4N)0.5[Ni(dmit)2]
Reizo KatoTakehiko MoriAkiko KobayashiYukiyoshi SasakiHayao Kobayashi
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1984 Volume 13 Issue 1 Pages 1-4

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Abstract

The crystal of (Et4N)0.5[Ni(dmit)2] belongs to triclinic system (dmit: isotrithionedithiolate). In the crystal, face-to-face stacking and side-by-side arrangement of Ni(dmit)2 molecules form the two-dimensional S···S networks, which are weakly connected in the third direction by thioketone sulfur atoms in the isotrithione ring. The electrical conductivity measurements show that (Et4N)0.5[Ni(dmit)2] is a semiconductor with small anisotropy.

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