Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
ELECTROLYTIC REDUCTION OF 1-METHYLSULFINYL-1-METYLTHIO-2-ARYLETHENES AT MERCURY AND PLATINUM ELECTRODES IN ACETONITRIL
Akira KunugiKyo Abe
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1984 Volume 13 Issue 2 Pages 159-162

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Abstract

The electrolytic reduction of 1-methylsulfinyl-1-methylthio-2-arylethenes involves a cleavage of one carbon–sulfur bond, resulting in formation of E-1-methylthio-2-arylethenes in good yields, but not Z-isomers, in the presence of excess phenol as a proton donor.

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