Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
COORDINATIVE ADDITION REACTIONS OF TERTIARY PHOSPHINES TO BISPHOSPHINE- AND BISPHOSPHITEPALLADIUM(O) COMPLEXES. FORMATION OF FOURCOORDINATE PALLADIUM(O) SPECIES WITH C3v-SYMMETRY
Hisao UrataTatsuyuki TsukuiHiroharu SuzukiYoshihiko Moro-OkaTsuneo Ikawa
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1984 Volume 13 Issue 2 Pages 191-194

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Abstract

Low-temperature 31P-NMR studies of the coordinative additions of tertiary phosphines, Ph2MeP and Et3P, to twocoordinate palladium(O) complexes, (Ph3P)2Pd(O) and [(PhO)3P]2pd(O), in toluene-d8 show the formation of fourcoordinate complexes with C3v-symmetry, (Ph2MeP)3(Ph3P)Pd and (Et3P)[(PhO)3P]3Pd, respectively.

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