Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
REDOX BEHAVIOR OF METHYLVIOLOGEN CATION RADICAL INCORPORATED INTO A HYDROPHOBIC ORGANIC PHASE BY LIPOPHILIC STABLE ANIONS
Keisuke TakumaTakaaki SonodaHiroshi Kobayashi
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JOURNALS FREE ACCESS

1984 Volume 13 Issue 2 Pages 243-246

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Abstract

Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (TFPB) could incorporate methylviologen radical cation (MV) and dication (MV2+) into hydrophobic organic solvent, while 2-hydroxy-3,5-ditert-butylbenzenesulfonate (HBBS) could hold only the radical cation in the organic solvent. MV incorporated with TFPB could easily transfer the electron to an acceptor at the interface between the organic and aqueous phases, and played the role of an efficient catalytic electron mediator across an organic liquid membrane.

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