1984 Volume 13 Issue 2 Pages 255-258
The [2,3]-Wittig rearrangement of enantiomerically-enriched α-methylallyl propargyl ethers provides a high degree (ca. 90%) of 1,4-chirality transfer, together with 95–98% of (E)-selectivity. The observed sense of 1,4-chirality transfer is discussed on mechanistic grounds.
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