Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
N-(TRIMETHYLSILYLMETHYL) PYRIDINIUM TRIFLUOROMETHANESULFONATES AS FACILE PRECURSORS FOR NONSTABIL1ZED PYRID1NIUM METHYLIDES
Otohiko TsugeShujf KanemasaSatoru KuraokaShigeorf Takenaka
Author information
JOURNALS FREE ACCESS

1984 Volume 13 Issue 2 Pages 279-280

Details
Abstract

As facile precursors for nonstabilized pyridinium methylides N-(trimethylsilylmethyl)pyridinium triflates were synthesized. Cesium fluoride induced desilylation of the precursors liberated the nonstabilized pyridinium methylides which were trapped as the cycloadducts to dimethyl acetylenedicarboxylate.

Information related to the author

This article cannot obtain the latest cited-by information.

© The Chemical Society of Japan
Previous article Next article
feedback
Top