Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
PHOTOCHEMICAL GEOMETRICAL ISOMERIZATION OF A C=C-C=N SYSTEM. BEHAVIOR OF THE FOUR STEREOISOMERS OF 1-METHOXYIMINO-3-PHENYL-2-PROPENE
Akiko OkamiTatsuo AraiHirochika SakuragiKatsumi Tokumaru
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1984 Volume 13 Issue 2 Pages 289-292

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Abstract

Irradiation of the four isomers, trans-anti, trans-syn, cis-anti, and cis-syn, of 1-methoxyimino-3-phenyl-2-propene, a conjugated imine, resulted in cis-trans, syn-anti, and concurrent cis-trans and syn-anti isomerization. The photostationary isomer ratio and the quantum yields of the isomerization from each isomer were determined to elucidate the mechanism of the isomerization.

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