1986 Volume 15 Issue 1 Pages 93-96
Crystal of the semiconducting salt of α′-(BEDT-TTF)2BrICl has a modified structure of metallic α-(BEDT-TTF)2I3. Unlike the molecules in α-(BEDT-TTF)2I3, all the molecules are on the general positions. The average molecular planes of two crystallographically independent BEDT-TTF molecules are not parallel. The dihedral angle between them is 48°. A two-dimensional sulfur network is formed by the intermolecular short S···S contacts.
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