Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Highly Stereoselective Photoisomerization of all-trans Naphthyl Retinal Analog to the 11-cis Isomer by Protein Mediation
Kazuo TsujimotoKen OhmuraMamoru OhashiReiko HaraTomiyuki HaraKoichi OzakiMasakatsu Watanabe
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1986 Volume 15 Issue 12 Pages 2005-2008

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Abstract

Protein-mediated photoisomerization of all-trans Np-retinal stereospecifically gave the 11-cis isomer whose structure was determined, whereas irradiation of all-trans Np-retinal in acetonitrile furnished the four isomers, none of which was the 11-cis isomer.

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