Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Determination of the Absolute Configuration of u-fac-[Co(ida)(mdien)]+ by 1H NMR Spectroscopy
Tomoharu AmaSumio KaizakiHiroshi KawaguchiTakaji Yasui
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1987 Volume 16 Issue 3 Pages 441-444

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Abstract

Iminodiacetic acid containing asymmetric carbon with S chirality (H2ida(Cs); HOOCCH2NHC*HDCOOH) was prepared by stereospecific deuteration of (−)563CD-mer(O)cis(Nc)-[Co(ida)(edma)]. Using this H2ida(Cs), u-fac-[Co(ida(Cs))(mdien)]+ was prepared and optically resolved. On the basis of the 1H NMR spectra of the chelating ida(Cs), the absolute configuration of the (−)550CD isomer was assigned to ΔΛΔ.

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