Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Crystal and Electronic Structures of a New Molecular Superconductor, κ-(BEDT-TTF)2I3
Akiko KobayashiReizo KatoHayao KobayashiShinji MoriyamaYutaka NishioKoji KajitaWataru Sasaki
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1987 Volume 16 Issue 3 Pages 459-462

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Abstract

The crystal of a new ambient-pressure superconductor, κ-(BEDT-TTF)2I3 belongs to the monoclinic system with space group P21/c and a=16.387, b=8.466, c=12.832 Å and β=108.56°. The 2-dimensional(2D) metal sheets composed of paired BEDT-TTF molecules and the I3 anion sheets are arranged alternately along the a. direction. The orientation of the neighbouring paired molecules is almost perpendicular to each other.

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