Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
A New Ambient-pressure Superconductor, κ-(BEDT-TTF)2I3
Reizo KatoHayao KobayashiAkiko KobayashiShinji MoriyamaYutaka NishioKoji KajitaWataru Sasaki
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1987 Volume 16 Issue 3 Pages 507-510

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Abstract

Electrochemical oxidation of a solution containing BEDT-TTF, (n-C4H9)4NI3,and small amount of (n-C4H9)4NAuI2 gave a new ambient-pressure superconductor (Tc=3.6 K), which coexisted with the superconducting θ-type salt but was clearly distinguished by the X-ray examination. The crystal data are: (C10H8S8)2I3, monoclinic, P21/c, a=16.387(4), b=8.446(2), c=12.832(8) Å, β=108.56(3)°, V=1687.6 Å3, Z=2.

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