Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Ring Expansion through [2+2] Photocycloaddition–β-Scission Sequence. Two Carbon Ring Expansions of β-Indanone and β-Tetralone
Hiroshi SuginomeMasahito ItohKazuhiro Kobayashi
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1987 Volume 16 Issue 8 Pages 1527-1530

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Abstract

We describe a new method for two carbon ring expansions of 5-and 6-membered rings of β-indanone and β-tetralone through the [2+2] photocycloaddition of the enol ethers of the cyclic ketones followed by the radical cleavage of the fused bond of the cyclobutanols derived from the adducts.

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