Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Nature of Metal-Olefin Bond in Neutral η3-Allyl (olef in)platinum(II) Complexes. In-plane Olefin Coordination and Stability Trend Unusually Weakly Dependent on Electronic Effect of Olefin-substituent
Hideo KurosawaHiroaki OhnishiKunio MikiNobutami KasaiKazuyuki TatsumiAkira Nakamura
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1987 Volume 16 Issue 8 Pages 1623-1626

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Abstract

Relative olefin coordination ability in Pt(η3-CH2CMeCH2)(CH2=CHC6H4Y)(C6F5)(2)was determined to show the stability trend unusually weakly dependent on the electronic property of the substituent Y. The crystal structure of the styrene complex 2 (Y= H) revealed the C=C bond oriented parallel to the coordination plane. The nature of Pt-olefin bond in 2 has been discussed in terms of these stability and structural trends.

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