Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
The First Molecular Superconductor Based on π-Acceptor Molecules and Closed-Shell Cations, [(CH3)4N][Ni(dmit)2]2, Low-Temperature X-Ray Studies and Superconducting Transition
Akiko KobayashiHyernjoo KimYukiyoshi SasakiReizo KatoHayao KobayashiShinji MoriyamaYutaka NishioKoji KajitaWataru Sasaki
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1987 Volume 16 Issue 9 Pages 1819-1822

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Abstract

Low-temperature structural study of [(CH3)4N][Ni(dmit)2]2 suggested that the rotational freedom of methyl group seems to play an important role in the “metal-semimetal” transition. Superconducting transition was observed at 5 K (7 kbar).

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