Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
A NOVEL FRAGMENTATION OF RING A IN 6α-HYDROXY-7-OXOABIETA-8,11,13-TRIENE AND FORMATION OF A β-NAPHTHOL DERIVATIVE
Takashi MatsumotoSachihiko ImaiHideto MasudaKenji Fukui
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1974 Volume 3 Issue 9 Pages 1001-1004

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Abstract

In order to examine the fragmentation reaction of tricyclic diterpenoids, 6α-hydroxy-7-oxoabieta-8,11,13-triene (V) was prepared from 7-oxoabieta-8,11,13-triene (XI) via an enol acetate (XII). After V was treated with p-toluenesulfonyl chloride, the product was heated at 200°C to afford a β-naphthol derivative (IX).

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