Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
A STABILITY-SELECTIVITY RELATIONSHIP FOR PHENOLYSES OF ALKYL CHLORIDES AND p-NITROBENZOATES
Kunio OkamotoTomomi Kinoshita
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1974 Volume 3 Issue 9 Pages 1037-1040

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Abstract

The existence of a linear free-energy relationship between the phenolic reactivity and the selectivity for attack of the phenol molecule on carbonium ion intermediates has been established for the titled substrates. The examples are the first ones for the reaction between the carbonium ions and an ambident molecule.

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