Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
NUCLEAR MAGNETIC RESONANCE STUDY OF EXCHANGING SYSTEMS. VII. 13C NMR SPECTRA OF BARBARALONE AND ITS DEGENERATE COPE REARRANGEMENT
Hiroshi NakanishiOsamu Yamamoto
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1975 Volume 4 Issue 6 Pages 513-516

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Abstract

13C NMR spectra of barbaralone were measured at several temperatures. Spin-lattice relaxation times and nuclear Overhauser enhancement factors were also determined. Complete line shape analyses of 13C spectra were made by the simulation method to obtain the accurate activation parameters of the Cope rearrangement of barbaralone.

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