Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
PHOTOCHEMICAL REACTION OF 3-HEXENE-2,5-DIONE WITH TETRAMETHYLETHYLENE: STEREOSPECIFIC SYNTHESIS OF TRANS-1,2-DIACETYL-3,3,4,4-TETRAMETHYLCYCLOBUTANE
Zen-ichi YoshidaMakoto KimuraShigeo Yoneda
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1975 Volume 4 Issue 6 Pages 519-522

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Abstract

Photochemical reaction of 3-hexene-2,5-dione (1) with tetramethylethylene has been found to lead to stereospecific formation of trans-1,2-diacetyl-3,3,4,4-tetramethylcyclobutane. No evidence for oxetane formation has been obtained.

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