Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
KINETICS ON THE SULFONATION REACTION OF 1-DODECENE WITH SODIUM HYDROGENSULFITE
Akihisa SakumotoTeijiro MiyataMasamitsu Washino
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1975 Volume 4 Issue 6 Pages 563-566

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Abstract

The kinetics on the radiation-induced addition of hydrogensulfite to 1-dodecene was investigated in the presence of a surfactant, 1-dodecanesulfonate, in an aqueous solution of t-butyl alcohol. The termination was found to be the reaction of 1-dodecanesulfonate radical with sulfite radical ion. This result was deduced to be due to the micellar effect.

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