Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
STUDIES ON THE MICHAEL-TYPE REACTION OF S-VINYL SULFILIMINE
Tamotsu YamamotoMakoto Okawara
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1975 Volume 4 Issue 6 Pages 581-584

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Abstract

S-Phenyl-S-vinyl-N-tosyl-sulfilimine (3) was synthesized and the Michael type reactions of (3) with various nucleophiles such as thiols, dithiocarbamate, alcohols, amines and malononitrile were investigated. The adducts (4) obtained were pyrolyzed to give the vinyl compounds (7) together with sulfenamide (8) in good yield.

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