Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
THE ELECTRON TRANSFER REACTION BETWEEN WURSTER’S BLUE CATION AND N,N-DIMETHYL-P-PHENYLENEDIAMINE IN AQUEOUS SOLUTION
Akihiko Yamagishi
Author information
JOURNALS FREE ACCESS

1975 Volume 4 Issue 6 Pages 595-598

Details
Abstract

The electron transfer reaction between Wurster’s Blue cation (TMPD\underset.+) and N,N-dimethyl-p-phenylenediamine (DMPD) in aqueous solution is investigated by the temperature-jump method. The forward and backward rate constants of TMPD\underset.+ + DKPD \ ightleftharpoons TMPD + DMPD\underset.+ are determined to be (4.2±2)×106 and (1.5±0.5)×108 M−1 s−1 at 10±2°C, respectively.

Information related to the author

This article cannot obtain the latest cited-by information.

© The Chemical Society of Japan
Previous article Next article
feedback
Top