Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
REACTIONS OF ISOCYANIDE-PALLADIUM(II) COMPLEXES WITH NITRILIMINES. NOVEL CYCLIC CARBENE-PALLADIUM(II) COMPLEXES
Katsuma HirakiYoshio FuchitaShigeki Morinaga
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1978 Volume 7 Issue 1 Pages 1-2

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Abstract

cis-[PdCl2(PPh2R)(CN–C6H4–CH3p)] (R=Ph or Et) reacted with nitrilimines, derived from N-phenylarylcarbohydrazonyl chlorides and triethylamine, to afford novel cyclic carbene-palladium(II) complexes, cis-[PdCl2(PPh2R){CN(C6H4–CH3p)C(C6H4R′−p)=N-NPh}].

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