Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
ADDITION OF CARBON TETRACHLORIDE TO CONJUGATED 1,3-DIENES CATALYZED BY DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
Hideyuki MatsumotoTaichi NakanoToshimi NikaidoYoichiro Nagai
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1978 Volume 7 Issue 1 Pages 115-116

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Abstract

Addition of carbon tetrachloride to conjugated 1,3-dienes such as 1,3-butadiene, 1,3-pentadiene, isoprene, 1,3-cyclohexadiene and 1,3-cyclooctadiene proceeded smoothly under mild conditions in the presence of dichlorotris(triphenylphosphine)ruthenium(II) to give the corresponding 1,4-addition products as 1:1 adducts in excellent yields.

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