Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
POSSIBLE IMPORTANCE OF AN ABNORMAL ORBITAL INTERACTION IN EXCITED-STATE REACTIONS BETWEEN ELECTRON DONORS AND ACCEPTORS
Satoshi InagakiYoshio Hirabayashi
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1978 Volume 7 Issue 2 Pages 135-138

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Abstract

Photochemical reactions between powerful electron donors and acceptors are likely controlled by the (HOMO)D–(LUMO)A interaction involved in the D*A–D+*A or DA*–D+A* interaction, the frontier orbital interaction being the same as one in usual thermal reactions.

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