Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
FLUORINATION OF ACTIVATED HALOGENS WITH KF IN POLYETHYLENE GLYCOL-ACETONITRILE SYSTEM
Tomoya KitazumeNobuo Ishikawa
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1978 Volume 7 Issue 3 Pages 283-284

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Abstract

Polyethylene glycol (mol. wei. 300–600) was found to be effective as a phase-transfer catalyst on the fluorination of activated halogen compounds with potassium fluoride in acetonitrile. Carboxylic and sulfonic acid chlorides were readily converted into their fluorides in high yields.

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