Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
DIVERSITY IN THE BASE-INDUCED PHOTOREACTIONS OF 3-ACETYL-2,4-DIOXOTHIOLANE (3-ACETYLTHIOTETRONIC ACID)
Kimitoshi SaitoTadashi Sato
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1978 Volume 7 Issue 3 Pages 307-310

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Abstract

Base-induced photolysis of 3-acetyl-2,4-dioxothiolane (3-acetylthiotetronic acid) undergoes (a) reductive ring cleavage or (b) two types of fragmentation with carbon-skeleton rearrangement, depending upon the irradiation conditions. Conceivable reaction schemes were presented.

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