Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
ON THE REVERSIBILITY OF METAL CARBENE FORMATION PROCESS IN OLEFIN METATHESIS REACTION OVER MoOx /β-TiO2 CATALYST
Katsumi TanakaKoshiro MiyaharaKen-ichi Tanaka
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JOURNALS FREE ACCESS

1980 Volume 9 Issue 6 Pages 623-626

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Abstract

Co-isomerization of d0- and d8-cis-2-butene was carried out on a novel catalyst, MoOx/β-TiO2(2.9>x>2.3), which is active for olefin metathesis reaction without inter- and intra-molecular hydrogen scrambling of olefins. The ratio, d4/(d0+d8), in produced trans-2-butene was found to be zero at the initial stage of the reaction, indicating a type of cis–trans isomerization by intra-molecular metathesis.

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