Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
THE FORMATION OF α- AND β-ALANINE BY THE INSERTION OF NH(1Δ) RADICALS INTO THE C-H BONDS OF PROPIONIC ACID
Shin SatoTakashi KitamuraShigeru Tsunashima
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1980 Volume 9 Issue 6 Pages 687-690

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Abstract

The formation of α- and β-alanine in the photolysis of hydrogen azide in propionic acid was confirmed by the NMR spectra. The yield ratios, alanine/nitrogen and β/α in alanine were found to be 0.4 and 1.5, respectively, suggesting that NH(1Δ) radicals insert into the C–H bonds of propionic acid.

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