Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
ELECTROSTATIC AND HYDROPHOBIC EFFECTS OF 1-1 ELECTROLYTES ON THE REACTIONS BETWEEN CHLOROCOBALT(III) COMPLEXES AND MERCURY(II) IONS
Masayasu IidaHideo Yamatera
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1980 Volume 9 Issue 6 Pages 693-694

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Abstract

The Hg 2+-assisted aquation of cis-[CoCl(OH2)(phen)2]2+ was retarded by sodium methanesulfonate and benzenesulfonate(0.5–1.0 mol dm−3), while they accelerated a similar reaction of [CoCl(NH3)5]2+.The unusual retardation effect has been attributed to the hydrophobic interaction of the complex ion and the organic sulfonate ions.

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