Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
SYNTHESIS OF OLEFINS BY NICKEL-CATALYZED DECARBONYLATION OF S-(2-PYRIDYL) THIOATES
Toshio GotoMakoto OnakaTeruaki Mukaiyama
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1980 Volume 9 Issue 6 Pages 709-712

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Abstract

S-(2-Pyridyl) thioates, especially derived from secondary and tertiary carboxylic acids, are decarbonylated by use of a catalytic amount of nickel chloride and zinc powder to give olefins in good yields.

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