Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
RHODIUM CATALYZED CARBONYLATION REACTIONS OF CYCLOPROPANES
Masanobu HidaiMasami OrisakuYasuzo Uchida
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1980 Volume 9 Issue 6 Pages 753-754

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Abstract

Cyclopropane was carbonylated by [Rh(CO)2Cl]2 under carbon monoxide pressure to give cyclobutanone, dipropyl ketone, propyl isopropyl ketone, and 2- or 3-methylcyclohexanone. Some other cyclopropane derivatives were also examined. Norcarane gave a small amount of bicyclo[4.2.0]octa-7-one, though phenylcyclopropane did not give any carbonylation products. The formation of polyketone was efficient in the case of methylenecyclopropane.

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