Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on Digitalis Glycosides. XI. Isolation of Digipronin, Purpnin, and Purpronin.
佐藤 大助石井 宏尾山 蓉子奥村 保
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1962 年 10 巻 1 号 p. 37-42

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Three new digitanol glycosides (digipronin, purpnin, and purpronin) were isolated from the water-soluble fraction of the leaves of Digitalis purpurea L. On hydrolysis, digipronin gave three aglycones (α-, β- and γ-digiprogenin) and one molecule of d-digitalose, and purpnin and purpronin gave purpnigenin and purprogenin respectively together with three molecules of d-digitoxose. It is likely that these aglycones belong to a C21-steroid of pregnenolone type. A method for distinguishing the diginigenin type and the pregnenolone type of digitanol glycosides was also described.
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© The Pharmaceutical Society of Japan
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