Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
Photo-induced Friedel-Crafts Reaction.II
OSAMU YONEMITSUSHUNJI NARUTO
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Volume 19 (1971) Issue 6 Pages 1158-1163

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Abstract

On photolysis of anisol or phenol with chloroacetamide, methoxy-or hydroxyacetamides were easily obtained. This reaction is one of alkylation on aromatic ring with alkyl halide in very mild condition and provides an example of photo-induced Friedel-Crafts reaction. A photorearrangement of phenoxyacetamide to hydroxyphenylacetamides in good yield was observed. Some discussion for mechanisms of these reactions were also described.

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