Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
AN EFFICIENT CONSTRUCTION OF 1, 2-TRANS-β-GLYCOSIDIC LINKAGES VIA BENZYL-PROTECTED GLYCOPYRANOSYL P, P-DIPHENYL-N-(p-TOLUENESULFONYL)-PHOSPHINIMIDATES
Shun-ichi HASHIMOTOTakeshi HONDAShiro IKEGAMI
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1990 Volume 38 Issue 8 Pages 2323-2325

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Abstract

An efficient 1, 2-trans-glycosidation reaction withon neighbouring group participation has been developed using benzyl-protected P, P-diphenyl-N-(p-toluensulfonyl)phosphinimidates as glycosyl donors in the presence of trimethylsilyl triflate or boron trifluoride etherate.

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© The Pharmaceutical Society of Japan
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