Formation of 9, 25-Cyclofernane by Reductive Homoallylic Cyclization of Fern-9(11)-en-25-ol Mesylate

Yoshinori FUJIMOTO; Chikako MURASAKI; Tadashi EGUCHI; Katsumi KAKINUMA; C. P. DUTTA

doi:10.1248/cpb.42.1334

著者情報

キーワード: 9, 25-cyclofernane, cyclopropane triterpene, reductive cyclization, homoallylic mesylate, lithium aluminum hydride

ジャーナルフリー

1994 年 42 巻 6 号 p. 1334-1335

DOI https://doi.org/10.1248/cpb.42.1334

詳細

抄録

Treatment of fern-9(11)-en-25-ol mesylate (2) with LiAlH₄ in refluxing tetrahydrofuran afforded 9, 25-cyclofernane(4), a new cyclopropane ring-containing triterpene, in a moderate yield.

責任著者(Corresponding author)

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